Van Bommel, in his first press conference since his appointment late last month, said he jumped at the offer to replace Rudi Garcia as Belgium coach.
"Did I want to wait for the Dutch national team? No, not at all. I didn't even think about that," he said on Friday.
"As a coach, being in charge of a national team is one of the best jobs there is. You work with the best players in a country. And there aren't that many really top countries.
"I am very happy to be here. It is different from coaching a club, but this challenge suits me well.
"In the past two years, I have had many offers, but none that I was convinced of. Things have moved very quickly here. Coaching a country, and certainly Belgium, is an honour. Every coach wants to do this."
Belgium reached the World Cup quarter-finals last month, but Garcia did not have his contract renewed, with Van Bommel, a former defender with Barcelona, Bayern Munich and AC Milan and who played for the Dutch in the 2010 World Cup final, quickly named as his replacement.
Van Bommel, 49, said winning was top of his agenda. "As a footballer and a coach, you always want to win," he told reporters.
"You don't know what will happen along the way, but you want to go as far as possible. In the Netherlands, they often say: 'We are going to be world champions'. However, there are quite a few factors involved.
"So I don't want to go around shouting that we are going to win the European Championship, even though that is the reason why we are playing."
Belgium will start first, however, with the Nations League and Van Bommel's debut as coach is against Italy in Rome on September 25, followed by two matches against Turkey and one against France in the September-October international window.
Van Bommel was repeatedly asked whether he might try to persuade goalkeeper Thibaut Courtois, who said after the World Cup he wanted a break from the national team, to keep playing.
"We are going to talk to Thibaut first without passing judgment. He has given his opinion, and at this moment, we are not going to decide about it. That wouldn't be right if you have only spoken to each other once," the new coach said.
"Perhaps he has already revised his opinion. As soon as he is back in full training, we will fly there and talk."