Urena made his debut for Girona two years ago as an 18 year-old and has spent the past seasons on-loan with Cartagena and Leganes.
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With Leganes last season, Urena played 19 games, helping them earn promotion back to the Primera. He has signed a two-year deal with Barca.
Urena has just completed an Olympics campaign with the Domenican Republic.
He will initially be registered with Barca Atletic.