The Canucks took an early lead when Tanzania defender Ester Masek inadvertently turned the ball into her own net.
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Canada came out firing after the break, scoring twice within five minutes. Olivia Chisholm produced a stunning long-range strike that could contend for Goal of the Tournament before Annabelle Chukwu doubled the advantage from close range.
With 50 students from a local Canadian school in Katowice cheering them on, Chukwu added her second with a powerful finish.
Kaylee Hunter and Liana Tarasco completed the rout late on as Canada moved to four points and await confirmation of their knockout-stage qualification as one of the best third-placed teams.