The Italy U19 international moves to PSG as a free transfer, with his contract to expire at the end of June.
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Marin, 18, will sign a five-year contract with PSG on July 1, says L'Equipe.
The youngster will move to PSG as senior third-choice keeper and work with fellow Italian Gigio Donnarumma.
Marin moved to Roma in 2022 and is Brazilian born and raised, though holds Italian citizenship.