The Holland international is set to join the Azzurri on-loan for the season with an option to buy.
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TMW says Hojlund has just completed his medical at Villa Stuart today with an announcement due.
Hojlund will arrive as cover for injured centre-forward Romelu Lukaku.
Napoli will pay €6m in terms of a loan fee plus €44m should they trigger a permanent option.
After victory over Cagliari on Saturday, Napoli coach Antonio Conte said: "Hojlund should also arrive as a replacement for Lukaku. We're trying to do things the right way, knowing that we're completing a squad that wasn't there last year to compete in the competitions we have this year."