Wojciech Szczesny stepped up to make his competitive debut for Barca in their Spanish Supercopa semifinal win against Athletic Bilbao.
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Barca won 2-0, with the Pole keeping a clean sheet.
Marca says Pena was dropped for being late to a team talk ahead of the tie.
It was the first game Pena has missed since he stepped up to replace the injured Marc-Andre ter Stegen earlier this season.