Calciomercato.com says United had scouts posted on Sunday to check on Leao in Milan's 0-0 draw with Juventus.
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Leao has less than two years left on his Rossonero contract and Milan would be willing to sell this summer for the right price.
An offer of €60m would be enough to bring Milan to the negotiating table.
Leao has scored nine goals in 26 Serie A appearances this season, also laying on three assists.
Sunday night’s draw saw Milan stay third on the Serie A table.