The Greece left-back is on a season-long deal with the Giallorossi.
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However, with Liverpool in the process of selling Andrew Robertson to Tottenham, the Reds want to bring back Tsimikas back to Anfield as cover for Milos Kerkez.
Roma won't stand in Liverpool's way. with Tsimikas struggling to win over coach Gian Piero Gasperini this season.
At Liverpool, Tsimikas' deal expires at the end of the season.