Leipzig led 1-0 at half-time through Romulo Cardoso, leaving Bayern searching for inspiration. That spark arrived after the break as Serge Gnabry equalised before Kane struck in the 67th minute, finishing clinically from close range after a pass from Michael Olise.
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Bayern then took full control, with Jonathan Tah heading in from a corner and Aleksandar Pavlovic adding a fourth.
Olise capped an outstanding performance by providing another assist before scoring himself to complete the rout.
Kane’s influential goal helped ignite a dominant second half, as Bayern extended their unbeaten run in emphatic fashion.