It was a high octane affair as Real ranout winners 3-2 in a thriller.
During the match, Mourinho had a pop at Jordi Alba for a heavy challenge on Real midfielder Mesut Ozil. But the youngster did not hold back and snapped back at the Real coach.
Los Che veteran David Albelda also became involved exchanging words with the Portuguese before play resumed.
In the opposite dugout, Real ace Xabi Alonso also had an exchange of views with Valencia coach Unai Emery.