Wolves have qualified for the Europa League last-16 despite losing 3-2 to Espanyol.
Matt Doherty brought the scores level after Adama Traore scored either side of a brace from Jonathan Calleri.
However, Calleri popped up again in stoppage time to secure a winner for the hosts.
It was too little too late as Wolves secured a 6-3 aggregate win.
It is the first time Wolves have progressed to the last 16 of a major European competition for the first time since the 1971-72 Uefa Cup
The last-16 draw for takes place on Friday at 12:00 GMT.