The two teams will meet in the quarterfinals.
"Barcelona are a team I always watch," Pogba told Eurosport while on international duty with France for the Euro 2020 qualifiers.
"You can always learn as a midfielder, I like watching football. Their system, their culture...it can always help me.
"Barcelona is a great team, one of the best in the world. They have extraordinary players.
"It's a match where I want to have fun. Playing against one of the best teams in the world is always a pleasure. It's a team I lost against in the Champions League Final (in 2015 with Juventus ), but it's always good to play against the best."
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