The Reds were stunned by Atletico Madrid last week in the round of 16.
Discussing the Champions League, Mihajlovic stated: “[Jürgen] Klopp had to slip up sooner or later, it's the law of the large numbers. They have played an unrepeatable Premier League so far and will win by a triumph.
“Liverpool pursued the League title after so many years.
“Playing against the Atletico Madrid of Diego Simeone is always tough.