Confronted with questioning over his team's alleged gamesmanship and constant questioning of referee Rob Styles' decisions during a 1-1 draw at Anfield, Chelsea boss Mourinho claimed: "We are a naive and pure team.
"I have a naive team, they are naive because we do not have divers, we do not have violent people we do not have nasty tackles. We do not have people diving into swimming pools, Chelsea is a naive team. It is a pure team, that is my opinion."
On hearing the Portuguese coach's version of affairs, Liverpool chief Benitez could not stop himself hitting back.
He said: "I will not name people, but you can check their team and see how many times they do things that he (Mourinho) says that they do not do.
"I don't want to give names but I remember a lot of situations in the last three years, and today you could see the players talking all the time at the referee."
Benitez was furious with the penalty decision that gave Frank Lampard a spot-kick equaliser after Florent Malouda had gone down under a challenge from Steve Finnan.
Benitez, whose £20million new signing Fernando Torres scored his first goal for the club in the first half, said: "What penalty? It was the invisible penalty. There were 45,000 people who could see it and know it wasn't, Jose says he could not see it.
"I want to have a lot of respect for referees, but sometimes I cannot understand why they give some decisions, that decision is impossible to explain.
"We had chances to win and we have two less points, we must now be positive. It is too early to say who are contenders, but we always show when we play Chelsea that we can be there, so now we have to be consistent against the rest of the teams for nine months."