The Serbian, who was twice linked with a move to Parkhead in the 1990s, was last in charge of a team eight years ago.
"I'm available at the moment. It would be something very special and I know I am capable," he told BBC Scotland.
Golac was speaking at Hampden Park, the scene of his greatest triumph in management: the 1994 Scottish Cup final victory over Rangers.
However, having left a position as technical director of the Libyan Football Association, he now feels he is the man to take Celtic forward.
"I would do a lot of big things for Celtic and put them where they belong: among the best in the world," he said.