Deportivo La Coruna have been relegated after defeat to Valencia.
Depor's 2-0 defeat will see them in the Segunda Liga next season.
Real Zaragoza's 2-1 win at Levante lifted them out of the bottom three at the expense of Depor, who finished a point from safety.
Aritz Aduriz put Valencia ahead in the fourth minute and the hosts' fate was sealed when Roberto Soldado grabbed a second deep into stoppage time.
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